Pavement materials: Bitumen
Lecture notes in Transportation Systems Engineering
3 August 2009
Bituminous materials or asphalts are extensively used for roadway
construction, primarily because of their excellent binding characteristics and
water proofing properties and relatively low cost.
Bituminous materials consists of bitumen which is a black or dark coloured
solid or viscous cementitious substances consists chiefly high molecular weight
hydrocarbons derived from distillation of petroleum or natural asphalt,
has adhesive properties, and is soluble in carbon disulphide.
Tars are residues from the destructive distillation of organic substances such
as coal, wood, or petroleum and are temperature sensitive than bitumen.
Bitumen will be dissolved in petroleum oils where unlike tar.
bitumen is the residue or by-product when the crude petrolium is refined.
A wide variety of refinery processes, such as the straight
distillation process, solvent extraction process etc.
may be used to produce bitumen of different consistency and other desirable
properties.
Depending on the sources and characteristics of the crude oils and on the
properties of bitumen required, more than one processing method may be
employed.
In the vacuum-steam distillation process the crude oil is heated and is introduced into a large cylindrical still.
Steam is introduced into the still to aid in the vapourisation of the more
volatile constituents of the petroleum and to minimise decomposition of the
distillates and residues.
The volatile constituents are collected, condensed, and the various fractions
stored for further refining, if needed.
The residues from this distillation are then fed into a vacuum distillation
unit, where residue pressure and steam will further separate out heavier gas
oils.
The bottom fraction from this unit is the vacuum-steam-refined asphalt cement.
The consistency of asphalt cement from this process can be controlled by the
amount of heavy gas oil removed.
Normally, asphalt produced by this process is softer.
As the asphalt cools down to room temperature, it becomes a semi solid
viscous material.
Normal practice is to heat bitumen to reduce
its viscosity.
In some situations preference is given to use liquid binders such as cutback
bitumen.
In cutback bitumen suitable solvent is used to lower the viscosity of the
bitumen.
From the environmental point of view also cutback bitumen is preferred.
The solvent from the bituminous material will evaporate and the bitumen will
bind the aggregate.
Cutback bitumen is used for cold weather bituminous road construction and
maintenance.
The distillates used for preparation of cutback bitumen are naphtha, kerosene,
diesel oil, and furnace oil.
There are different types of cutback bitumen like rapid curing (RC), medium
curing (MC), and slow curing (SC).
RC is recommended for surface dressing and patchwork.
MC is recommended for premix with less quantity of fine aggregates.
SC is used for premix with appreciable quantity of fine aggregates.
Bitumen emulsion is a liquid product in which bitumen is
suspended in a finely divided condition in an aqueous medium and stabilised by
suitable material.
Normally cationic type emulsions are used in India.
The bitumen content in the emulsion is around 60% and the remaining is water.
When the emulsion is applied on the road it breaks down resulting in release of
water and the mix starts to set.
The time of setting depends upon the grade of bitumen.
The viscosity of bituminous emulsions can be measured as per IS: 8887-1995.
Three types of bituminous emulsions are available, which are
Rapid setting (RS),
Medium setting (MS), and
Slow setting (SC).
Bitumen emulsions are ideal binders for hill road construction.
Where heating of bitumen or aggregates are difficult.
Rapid setting emulsions are used for surface dressing work.
Medium setting emulsions are preferred for premix jobs and patch repairs work.
Slow setting emulsions are preferred in rainy season.
In bituminous primer the distillate is absorbed by the road surface on which it
is spread.
The absorption therefore depends on the porosity of the surface.
Bitumen primers are useful on the stabilised surfaces and water bound macadam
base courses.
Bituminous primers are generally prepared on road sites by mixing penetration
bitumen with petroleum distillate.
Certain additives or blend of additives called
as bitumen modifiers can improve properties of Bitumen and bituminous mixes.
Bitumen treated with these modifiers is known as modified bitumen.
Polymer modified bitumen (PMB)/ crumb rubber modified bitumen (CRMB) should be
used only in wearing course depending upon the requirements of extreme climatic
variations.
The detailed specifications for modified bitumen have been issued by IRC: SP:
53-1999.
It must be noted that the performance of PMB and CRMB is dependent on strict
control on temperature during construction.
The advantages of using modified bitumen are as follows
- Lower susceptibility to daily and seasonal temperature variations
- Higher resistance to deformation at high pavement temperature
- Better age resistance properties
- Higher fatigue life for mixes
- Better adhesion between aggregates and binder
- Prevention of cracking and reflective cracking
The desirable properties of bitumen depend on the mix type and
construction. In general, Bitumen should posses following desirable properties.
- The bitumen should not be highly temperature susceptible: during the
hottest weather the mix should not become too soft or unstable,
and during cold weather the mix should not become too brittle causing cracks.
- The viscosity of the bitumen at the time of mixing and compaction should
be adequate.
This can be achieved by use of cutbacks or emulsions of suitable grades or by
heating the bitumen and aggregates prior to mixing.
- There should be adequate affinity and adhesion between the bitumen and
aggregates used in the mix.
There are a number of tests to assess the properties of bituminous materials.
The following tests are usually conducted to evaluate different properties
of bituminous materials.
- Penetration test
- Ductility test
- Softening point test
- Specific gravity test
- Viscosity test
- Flash and Fire point test
- Float test
- Water content test
- Loss on heating test
It measures the hardness or softness of bitumen by measuring the depth in
tenths of a millimeter to which a standard loaded needle will penetrate
vertically in 5 seconds.
BIS had standardised the equipment and test procedure.
The penetrometer consists of a needle assembly with a total weight of 100g and a
device for releasing and locking in any position.
The bitumen is softened to a
pouring consistency, stirred thoroughly and poured into containers at a depth
at least 15 mm in excess of the expected penetration.
The test should be
conducted at a specified temperature of 25
C.
It may be noted that
penetration value is largely influenced by any inaccuracy with regards to
pouring temperature, size of the needle, weight placed on the needle and the
test temperature.
A grade of 40/50 bitumen means the penetration value is in
the range 40 to 50 at standard test conditions.
In hot climates, a lower
penetration grade is preferred.
The Figure 4.1 shows a schematic Penetration Test setup.
Figure 1:
Penetration Test Setup
 |
Ductility is the property of bitumen that permits it to undergo great deformation
or elongation.
Ductility is defined as the distance in cm, to which a standard
sample or briquette of the material will be elongated without breaking.
Dimension of the briquette thus formed is exactly 1 cm square.
The bitumen
sample is heated and poured in the mould assembly placed on a plate.
These
samples with moulds are cooled in the air and then in water bath at 27
C
temperature.
The excess bitumen is cut and the surface is leveled using a hot
knife.
Then the mould with assembly containing sample is kept in water bath of
the ductility machine for about 90 minutes.
The sides of the moulds are
removed, the clips are hooked on the machine and the machine is operated.
The
distance up to the point of breaking of thread is the ductility value which is
reported in cm.
The ductility value gets affected by factors such as pouring
temperature, test temperature, rate of pulling etc.
A minimum ductility value
of 75 cm has been specified by the BIS.
Figure 4.2 shows ductility moulds to be filled with bitumen.
Figure 2:
Ductility Test
 |
Softening point denotes the temperature at which the bitumen attains a
particular degree of softening under the specifications of test.
The test is
conducted by using Ring and Ball apparatus.
A brass ring containing test sample
of bitumen is suspended in liquid like water or glycerin at a given
temperature.
A steel ball is placed upon the bitumen sample and the liquid
medium is heated at a rate of 5
C per minute.
Temperature is noted when the
softened bitumen touches the metal plate which is at a specified distance
below.
Generally, higher softening point indicates lower temperature
susceptibility and is preferred in hot climates.
Figure 4.3 shows Softening Point test setup.
Figure 3:
Softening Point Test Setup
 |
In paving jobs, to classify a binder, density property is of great use.
In most
cases bitumen is weighed, but when used with aggregates, the bitumen is
converted to volume using density values.
The density of bitumen is greatly
influenced by its chemical composition.
Increase in aromatic type mineral
impurities cause an increase in specific gravity.
The specific gravity of
bitumen is defined as the ratio of mass of given volume of bitumen of known
content to the mass of equal volume of water at 27
C.
The specific gravity
can be measured using either pycnometer or preparing a cube specimen of bitumen
in semi solid or solid state.
The specific gravity of bitumen varies from 0.97
to 1.02.
Viscosity denotes the fluid property of bituminous material and it is a measure
of resistance to flow.
At the application temperature, this characteristic
greatly influences the strength of resulting paving mixes.
Low or high
viscosity during compaction or mixing has been observed to result in lower
stability values.
At high viscosity, it resist the compactive effort and
thereby resulting mix is heterogeneous, hence low stability values.
And at low
viscosity instead of providing a uniform film over aggregates, it will
lubricate the aggregate particles.
Orifice type viscometers are used to
indirectly find the viscosity of liquid binders like cutbacks and emulsions.
The viscosity expressed in seconds is the time taken by the 50 ml bitumen
material to pass through the orifice of a cup, under standard test conditions
and specified temperature.
Viscosity of a cutback can be measured with either
4.0 mm orifice at 25
C or 10 mm orifice at 25 or 40
C.
Figure 4:
Viscosity Test
 |
At high temperatures depending upon the grades of bitumen materials leave out
volatiles.
And these volatiles catches fire which is very hazardous and
therefore it is essential to qualify this temperature for each bitumen grade.
BIS defined the flash point as the temperature at which the vapour of bitumen
momentarily catches fire in the form of flash under specified test conditions.
The fire point is defined as the lowest temperature under specified test
conditions at which the bituminous material gets ignited and burns.
Normally the consistency of bituminous material can be measured either by
penetration test or viscosity test.
But for certain range of consistencies, these tests are not applicable and Float test is used.
The
apparatus consists of an aluminum float and a brass collar filled with bitumen
to be tested.
The specimen in the mould is cooled to a temperature of 5
C
and screwed in to float.
The total test assembly is floated in the water bath
at 50
C and the time required for water to pass its way through the
specimen plug is noted in seconds and is expressed as the float value.
It is desirable that the bitumen
contains minimum water content to prevent foaming of the bitumen when it is
heated above the boiling point of water.
The water in a bitumen is determined by mixing known weight of specimen in
a pure petroleum distillate free from water, heating and distilling of the
water.
The weight of the water condensed and collected is expressed as percentage by
weight of the original sample.
The allowable maximum water content should not be more than 0.2% by weight.
When the bitumen is heated it loses the volatility and gets hardened.
About 50gm of the sample is weighed and heated to a temperature of 163
C for
5hours in a specified oven designed for this test.
The sample specimen is weighed again after the heating period and loss in
weight is expressed as percentage by weight of the original sample.
Bitumen used in pavement mixes should not indicate more than 1% loss in
weight, but for bitumen having penetration values 150-200 up to 2% loss in
weight is allowed.
Table 1:
Tests for Bitumen with IS codes
Type of test |
Test Method |
Penetration Test |
IS: 1203-1978 |
Ductility test |
IS: 1208-1978 |
Softening Point test |
IS: 1205-1978 |
Specific gravity test |
IS: 1202-1978 |
Viscosity test |
IS: 1206-1978 |
Flash and Fire Point test |
IS: 1209-1978 |
Float Test |
IS: 1210-1978 |
Determination of water content |
IS: 1211-1978 |
Determination of Loss on heating |
IS:1212-1978 |
Requirements of bitumen as a binding material and its differrent forms were discussed.
Various tests are conducted on bitumen to assess its consistency, gradation, viscosity, temperature susceptibility, and safety.
Standard test procedures on bitumen were also covered in this chapter.
The minimum ductility value specified by BIS for bitumen is
- 50 cm
- 25 cm
- 75 cm
- 100 cm
The allowable maximum water content in bitumen should not be more than
by weight
by weight
by weight
by weight
The minimum ductility value specified by BIS for bitumen is
- 50 cm
- 25 cm
- 75 cm
- 100 cm
The allowable maximum water content in bitumen should not be more than
by weight
by weight
by weight
by weight
Prof. Tom V. Mathew
2009-08-03